84347-07-9Relevant academic research and scientific papers
Studies on as-Triazine Derivatives. XII. Synthesis of Alkenyl-1,2,4-triazine Derivatives
Konno, Shoetsu,Sagi, Mataichi,Takaharu, Etsuko,Fujimura, Satoshi,Hayashi, Kazuhiko,Yamanaka, Hiroshi
, p. 1721 - 1726 (2007/10/02)
3-Methyl-5,6-diphenyl-1,2,4-triazine (1) was treated with chlorine to give 3-trichloromethyl-5,6-diphenyl-1,2,4-triazine (2) as a sole product.On treatment with an excess (4.5 mol eq) of triphenylphosphine, 2 was transformed into α-(5,6-diphenyl-1,2,4-tri
STUDIES ON as-TRIAZINE DERIVATIVES. III. PREPARATION OF 3-ALKENYL-1,2,4-TRIAZINE DERIVATIVES BY MEANS OF WITTIG REACTION
Konno, Shoetsu,Takaharu, Etsuko,Aizawa, Yuichi,Yamanaka, Hiroshi
, p. 1869 - 1872 (2007/10/02)
The reaction of 3-trichloromethyl-5,6-diphenyl-1,2,4-triazine with triphenylphosphine proceeded reductively, and α-methylenetriphenylphosphorane was obtained as stable, yellow prisms.The phosphorane smoothly reacted with
