843613-09-2Relevant academic research and scientific papers
A one-pot reformatsky/cyclopropanation sequence induced by diethylzinc
Laroche, Marie-France,Belotti, Damien,Cossy, Janine
, p. 171 - 173 (2005)
(Chemical Equation Presented) A one-pot Reformatsky/cyclopropanation sequence induced by diethylzinc allows the transformation of ω-unsaturated ketones and aldehydes to ω-cyclopropyl alcohols.
Highly regioselective addition of an ester enolate equivalent to α,β-unsaturated ketones: Selective formation of both isomers derived from 1,2- and 1,4-additions using α-stannyl ester with additives
Yasuda,Matsukawa,Okamoto,Sako,Kitahara,Baba
, p. 2149 - 2150 (2007/10/03)
The reaction of α-stannyl ester with α,β-unsaturated ketones in the presence of stannous chloride (SnCl2) and chlorosilanes (Me3SiCl or Me2SiCl2) gave 1,2- and 1,4-addition products, respectively.
