84402-27-7Relevant academic research and scientific papers
SYNTHESIS OF SUBSTITUTED 1,3-DITHIOLANES FROM α,β-DIBROMO OXIMES
Tashchi, V. P.,Ivanov, A. P.,Rukasov, A. F.,Putsykin, Yu. G.,Orlova, T. I.,Baskakov, Yu. A.
, p. 1930 - 1937 (2007/10/02)
Derivatives of 1,3-Dithiolanes were obtained by the reaction of α,β-dibromo oximes, synthesized by bromination of the corresponding α,β-unsaturated oximes, with the salts of xanthic and dithiocarbamic acids and also with di(sodiothio)methylenemalononitrile and di(sodiothio)methylenecyanoethyl acetate.The bromine atom at the α position of the α,β-dibromo oximes undergoes substitution initially.The O-acyl derivatives of α,β-dibromo oximes underwent debromination under these conditions to the corresponding O-acylated α,β-unsaturated oximes.
