84411-66-5

Basic information

• Product Name: fac-W(CO)3(bis(diphenylphoshino)ethane)(acetone)
• CAS NO: 84411-66-5
• Molecular Weight: 724.385
• Mol File: 84411-66-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: fac-W(CO)3(bis(diphenylphoshino)ethane)(acetone)(CAS DataBase Reference)
• NIST Chemistry Reference: fac-W(CO)3(bis(diphenylphoshino)ethane)(acetone)(84411-66-5)
• EPA Substance Registry System: fac-W(CO)3(bis(diphenylphoshino)ethane)(acetone)(84411-66-5)

Safety Data

• Hazardous Substances Data: 84411-66-5(Hazardous Substances Data)

Upstream product

• 29890-05-9 tetracarbonyl-1,2-bis(diphenylphosphino)ethane-tungsten(0) 
• 14040-11-0 tungsten hexacarbonyl 
• 67-64-1 acetone 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Downstream Products

• 84471-89-6 fac-Tricarbonyl[bis(diphenylphosphino)ethan](methylacrylat)wolfram 
• 84411-62-1 mer-Tricarbonyl[bis(diphenylphosphino)ethan](methylacrylat)wolfram 
• 88035-90-9 mer-bis(diphenylphosphino)ethane(carbonyl)3tungsten(CC(H)Ph) 
• 180848-42-4 mer-[(1,2-bis(diphenylphosphino)ethane)(CO)3W=C=CHC=CH(CH₂)3] 
• 180848-43-5 mer-[(1,2-bis(diphenylphosphino)ethane)(CO)3W=C=CHC=CH(CH₂)5] 
• 84411-61-0 mer-Tricarbonyl[bis(diphenylphosphino)ethan](dimethylmaleat)wolfram 
• 84411-60-9 mer-Tricarbonyl[bis(diphenylphosphino)ethan](maleinsaeureanhydrid)wolfram 
• 84411-61-0 mer-Tricarbonyl[bis(diphenylphosphino)ethan](dimethylfumarat)wolfram 
• 98611-58-6 (OC)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CC((CH₂)3CH₃)CO₂CH₃) 
• 98586-67-5 Li⁽¹⁺⁾*(OC)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CC(CH₂)3CH₃)^(1-)=Li((OC)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CC(CH₂)3CH₃)) 
• 98586-64-2 Na⁽¹⁺⁾*(OC)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCCH₃)^(1-)=Na((OC)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCCH₃)) 
• 98586-68-6 Li⁽¹⁺⁾*(OC)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCC₆H₅)^(1-)=Li((OC)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCC₆H₅)) 
• 98586-59-5 Na⁽¹⁺⁾*(OC)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH)^(1-)=Na((OC)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CCH)) 
• 98586-71-1 (OC)3((C₆H₅)2PCH₂CH₂P(C₆H₅)2)W(CC(CH₃)CO₂CH₃) 

Relevant articles and documents

Synthesis and characterization of tungsten alkenyl-carbyne complexes [(dppe)(CO)2LW≡CCH=CCH2(CH2) nCH2CH2][BF4] (L = CO, MeCN, PMe3) and [(dppe)(CO)2XW≡CCH=CCH2(CH2]

Alkenyl-vinylidene complexes mer-[(dppe)(CO)3W=C=CHC=CH(CH2)nCH 2CH2] (dppe = 1,2-bis(diphenylphosphino)ethane; n = 1 (1a), n = 3 (1c), n = 4 (1d)) have been prepared by reaction of the complex fac-[(dppe)(CO)3W(Me2CO)] with 1-ethynylcyclopentanol, 1-ethynylcycloheptanol, and 1-ethynylcyclooctanol. Protonation at the Cδ of the alkenyl-vinylidene moiety with HBF4·OEt2 in diethyl ether or THF leads to the formation of cationic alkenyl-carbyne complexes mer-[(dppe)(CO)3W=CCH=CCH2(CH2) nCH2CH2][BF4] (n = 1 (2a), n = 3 (2c), n = 4 (2d)). When the protonation is carried out in CH2Cl2, isomeric carbyne complexes mer-[(dppe)(CO)3W≡CCH2C=CH(CH2) nCH2CH2][BF4] (2a′, 2c′, 2d′) are also generated. The alkenyl-carbyne complexes undergo carbonyl substitution by donor ligands to give dicarbonyl derivatives of the following types: (a) cationic complexes trans-[(dppe)(CO)2LW≡ CCH=CCH2(CH2)nCH2CH 2][BF4] (L = CH3CN, n = 1 (3a), n = 4 (3d); L = PMe3, n = 1 (4a), n = 4 (4d)) and (b) neutral complexes trans-[(dppe)(CO)2XW≡CCH=CCH2(CH2) nCH2CH2] (X = Cl, n = 1 (5a), n = 2 (5b), n = 3 (5c), n = 4 (5d); X = Br, n = 1 (6a), n = 4 (6d); X = I, n = 1 (7a), n = 3 (7c), n = 4 (7d)). The structure of complex 5a was determined by X-ray diffraction methods. The W atom displays a distorted octahedral coordination with the Cl atom [W-Cl = 2.540(1) A?] trans to the alkenyl-carbyne group [W≡C = 1.830(3) A?]. IR and 1H, 31P, 13C, and 183W NMR data are reported. The sequence for the trans influence in the order alkenyl-carbyne > alkenyl-vinylidene > CO could be found from the corresponding 1J(31P-183W) values. The low values for the alkenyl-carbyne groups are among the lowest ever reported, indicating a high trans influence of the carbyne group. 183W chemical shifts of compounds 1a-7a were obtained through two-dimensional indirect 31P, 183W recording techniques. A down field shifting of 183W resonances with decreasing π-acceptor ability of the ligands in complexes 2a-7a was observed.