84430-71-7Relevant academic research and scientific papers
TUNGSTEN AND MOLYBDENUM PHOSPHINE HEXAHYDRIDES: THE FIRST EXAMPLES OF NINE COORDINATION AMONG MONONUCLEAR MOLYBDENUM COMPLEXES
Crabtree, Robert H.,Hlatky, Gregory G.
, p. C21 - C23 (1982)
An improved preparation and some reactions of WH6(PMe2Ph)3 are described.This method has been extended to prepare the novel MoH6(PR3)3 compounds, the first mononuclear nine-coordinate molybdenum complexes.
Nine-coordinate hexahydride complexes of molybdenum and tungsten
Crabtree, Robert H.,Hlatky, Gregory G.
, p. 2388 - 2390 (2008/10/08)
The known complex WH6(PMe2Ph)3 is prepared in 53% yield from WCl4(PMe2Ph)3 and NaH2Al(OCH2CH2OMe)2 at -80°C. It reacts with RNC (R = t-Bu) to giv
