84434-00-4Relevant academic research and scientific papers
Conjugate Addition Reactions of Allylic Copper Species Derived from Grignard Reagents: Synthetic and Spectroscopic Aspects
Lipshutz, Bruce H.,Hackmann, Claus
, p. 7437 - 7444 (2007/10/02)
A general study on the 1,4-addition chemistry of allyl, methallyl, crotyl, and prenyl Grignard-derived organocopper reagents has been conducted.While diallylic cuprates formed from such species are not effective Michael donors, the 1:1:1 combination of an
Intramolecular Photochemical Reactions of 2-Acyl-1,5-hexadienes
Wolff, Steven,Agosta, William C.
, p. 1299 - 1304 (2007/10/02)
Photolysis of the 2-acyl-1,5-hexadienes 6-11 (Table I) leads to regiospecific crossed cyclization, yielding derivatives of bicyclohexane.Unlike dienones of the related classes 1 and 2, neither substitution at C(5) nor the presence of a ring influen
