84477-55-4

Basic information

• Product Name: [N(C₄H₉)4]⁽¹⁺⁾*[Au(C₆F₅)(C₆H₂F₃)2Br]^(1-)=[N(C₄H₉)4][Au(C₆F₅)(C₆H₂F₃)2Br]
• CAS NO: 84477-55-4
• Molecular Weight: 948.551
• Mol File: 84477-55-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [N(C₄H₉)4]⁽¹⁺⁾*[Au(C₆F₅)(C₆H₂F₃)2Br]^(1-)=[N(C₄H₉)4][Au(C₆F₅)(C₆H₂F₃)2Br](CAS DataBase Reference)
• NIST Chemistry Reference: [N(C₄H₉)4]⁽¹⁺⁾*[Au(C₆F₅)(C₆H₂F₃)2Br]^(1-)=[N(C₄H₉)4][Au(C₆F₅)(C₆H₂F₃)2Br](84477-55-4)
• EPA Substance Registry System: [N(C₄H₉)4]⁽¹⁺⁾*[Au(C₆F₅)(C₆H₂F₃)2Br]^(1-)=[N(C₄H₉)4][Au(C₆F₅)(C₆H₂F₃)2Br](84477-55-4)

Safety Data

• Hazardous Substances Data: 84477-55-4(Hazardous Substances Data)

Upstream product

• 75563-78-9 [Au(C₆F₅)(C₆H₂F₃)2(C₄H₈S)] 
• 1643-19-2 tetrabutylammomium bromide 

Relevant articles and documents

Tris(pentafluorophenyl)gold(III) Complexes

The preparation of (tht=tetrahydrothiophen) by oxidation of with is described.Displacement of tht by other neutral or anionic unidentate ligands leads to the synthesis of or Q .The compound adds amines to give the gold(III)-carbene complexes > (NR2=NHC6H4Me-p, NEt2, or NHCH2CH2NH2).The reaction of the compound with potentially bidentate ligands takes two different courses. (a) o-Phenylenebis(dimethylarsine) (pdma) and 1,2-bis(diphenylphosphino)methane (dppm) give four-co-ordinated complexes, in which the ligands are unidentate; the pdma complex has inequivalent methyl hydrogens at low temperature (1H n.m.r.) and the dppm complex inequivalent P atoms (31P n.m.r.).An X-ray structure of the pdma complex confirms four-co-ordination in the solid state; space group P21/n, a=10.796(3), b=17.347(6), c=16.275(5) Angstroem, β=94.47(3) deg, Z=4, R=0.058 for 3357 reflections. (b) 1,2-Bis(diphenylphosphino)ethane (dppe) acts as a bridging ligand leading to the formation of .Similar reactions starting from lead to the compounds or The arylation of (1-) or (1-) with Ag(C6F5) leads to (1-) and (1-) respectively.