75563-78-9

Upstream product

• 74625-70-0 thallium(III)⁽²⁴⁾Cl(6-C₆F₃H₂)2 

Downstream Products

• 84477-55-4 [N(C₄H₉)4]⁽¹⁺⁾*[Au(C₆F₅)(C₆H₂F₃)2Br]^(1-)=[N(C₄H₉)4][Au(C₆F₅)(C₆H₂F₃)2Br] 
• 131614-59-0 [N(C₄H₉)4]⁽¹⁺⁾*[Au(C₆F₅)2(C₆H₂F₃)2]^(1-)=[N(C₄H₉)4][Au(C₆F₅)2(C₆H₂F₃)2] 

Relevant academic research and scientific papers

CHLOROBIS(POLYFLUOROPHENYL)THALLIUM(III) COMPLEXES AND THEIR REACTIONS WITH GOLD(I) AND TIN(II) COMPOUNDS

The reaction of TlCl3 with RLi leads to complexes of the general formula TlR2Cl (R=C6F5, p-C6F4H, m-C6F4H, 2,4,6-C6F3H2, p-C6FH4 or m-CF3C6H4).Some of these undergo oxidative addition reactions with gold(I) complexes to give polyfluorophenyl derivatives of the types AuR2ClL and Au(C6F5)R2(tht) (tht=tetrahydrothiophen), and with SnCl2 to give oily materials from which stable solids of the general formula Q can be isolated by addition of QCl (Q=Et4N or Ph3BzP).