84508-35-0Relevant academic research and scientific papers
Ylide-Metal Complexes. VI. The Preparation and Properties of IVA-group Metal (Ge, Sn, Pb) Complexes of Alkylidenetriphenylphosphoranes
Yamamoto, Yoshihisa
, p. 3025 - 3026 (2007/10/02)
(Triphenylphosphonium alkylide)triphenylmetal chloride CHR-M(C6H5)3>Cl- (R: H, Me, i-pr; M: Ge, Sn, Pb) and (triphenylphosphonium alkylide)metal chloride CHR>nMCln-, (M=Ge, n=4; M=Pb, n=2) have been isolated from a reaction mixture of alkylidenetriphenylphosphoranes and IVA-group metal compounds.The ylide in CH2-Pb(C6H5)3>Cl- is bonded to the lead atom through the carbanionic donor atom.
