84518-62-7Relevant articles and documents
Efficient and Easy Access to Optically Pure Tetrasubstituted Tetrahydrofurans via Stereoselective Opening of C2-Symmetric Epoxide and Aziridine Rings
Kumar Kondapi, Venkata Pavan,Soueidan, Olivier-Mohamad,Hosseini, Seyedeh Nargess,Jabari, Nauras,West, Frederick G.
, p. 1367 - 1379 (2016/03/16)
An efficient and facile protocol to functionalize position C-3 of 2,5-anhydro-D-mannitol via diastereoselective ring opening of a C2-symmetric epoxide 2,5:3,4-dianhydro-D-allitol 3 has been developed. This method is protecting-group-free, high-
2,5-ANHYDRO-D-HEXITOLS: SYNTHESES OF 2,5-ANHYDRO-D-ALTRITOL AND 2,5-ANHYDRO-D-IDITOL
Otero, Dario A.,Simpson, Ronald
, p. 79 - 86 (2007/10/02)
2,5-Anhydro-D-altritol (2a) and the previously-unknown 2,5-anhydro-D-iditol (3a) have been prepared from 2,5-anhydro-D-mannitol (1a).The preparation of 3a from the intermediate epoxide 7b is particularly sensitive to pH, and a mechanism is proposed to explain this.Attention is drawn to the limitations of the trifluoroperacetic acid-disodium hydrogenphosphate procedure for the epoxidation of alkenes of diminished reactivity.