84519-69-7

Upstream product

• 1070-68-4 5-methyloctanoic acid 
• 84143-97-5 (-)-exo-bicyclo<3.2.1>oct-3-en-2-amine 
• 614-45-9 tert-Butyl peroxybenzoate 
• 823-02-9 bicyclo[3.2.1]oct-2-ene 
• 498-66-8 norborn-2-ene 
• 20507-56-6 bicyclo<2.2.2>oct-5-ene-2-exo-carboxylic acid 
• 172488-79-8 Trimethyl-((1S,2S,4S,5R)-tricyclo[3.2.1.0^2,4]oct-2-yloxy)-silane 
• 497-38-1 (1S,4R)-bicyclo[2.2.1]heptan-2-one 
• 35242-17-2 3-chlorobicyclo<3.2.1>oct-2-ene 
• 172488-80-1 (1R,2S,4S,6S)-3-Oxa-tricyclo[4.2.1.0^2,4]nonan-5-one 
• 172488-78-7 ((1S,4R)-Bicyclo[2.2.1]hept-2-en-2-yloxy)-trimethyl-silane 
• 79027-21-7 (+)-Bicyclo<3.2.1>oct-3-en-2-one 

Downstream Products

• 32222-49-4 endo-bicyclo<3.2.1>oct-3-en-2-ol 
• 4802-43-1 exo-bicyclo<3.2.1>oct-3-en-2-ol 
• 84519-70-0 (+)-exo-bicyclo<3.2.1.>oct-3-en-2-yl N-phenylcarbamate 

Relevant academic research and scientific papers

Asymmetric allylic oxidation of bridged-bicyclic alkenes using a copper-catalysed symmetrising-desymmetrising Kharasch-Sosnovsky reaction

Enantioselective symmetrising-desymmetrising allylic oxidation of racemic bridged bicyclic alkenes using an asymmetric copper-catalysed Kharasch-Sosnovsky reaction has been explored. Good yields and reasonable levels of induction (up to 70% ee) have been

Stereo- and Enantio-controlled Synthesis of (+)-Juvabione and (+)-Epijuvabione from (+)-Norcamphor

(+)-Juvabione and (+)-epijuvabione, natural sesquiterpenes exhibiting insect juvenile hormone activity, have been synthesized with complete stereo- and enantio-control using (+)-norcamphor as the chiral precursor via both the enantiomeric bicyclooc

2-Norbornanediazonium Ions Revisited

The reactions of 2-norbornanediazonium ions have been reinvestigated with the aid of optically active and deuterium-labeled precursors.Enantiomeric purities were determined by direct VPC methods, and deuterium distributions by 2H NMR spectroscopy.The product pattern is strongly affected by the polarity of the solvent. exo-Diazonium ions 13 in water yield racemic exo alcohol (s,kΔ) of the norbornadiazonium ions.Optically active exo products are typical of nonpolar solvents and originate most probably from assymetric ion pairs.Model studies with optically active bicyclooct-3-en-2-amine (36) provide conclusive evidence that ion-pair colapse may lead to optically active products even in the case of delocalized achiral carbocations.