84537-22-4

Upstream product

• 80785-72-4 tetramesityldisilene 
• 110698-83-4 1,1,2,2-tetramesityl-3-oxa-1,2-disilacyclopropane 
• 80785-74-6 1,1,2,2-tetramesityl-1,2-disiladioxetane 
• 130481-31-1 3,3,5,5-Tetrakis-(2,4,6-trimethyl-phenyl)-[1,2,4,3,5]trioxadisilolane 

Downstream Products

• 88589-59-7 bis(2,4,6-trimethylphenyl)silanol 
• 88589-60-0 C₃₆H₄₆O₂Si₂ 

Relevant academic research and scientific papers

Reactivity of the Sterically Demanding Siloxanediol Mes2Si(OH)(μ-O)Si(OH)Mes2 Towards Water and Ether Molecules

A series of isotopologues of the siloxanediol Mes2Si(OH)(μ-O)Si(OH)Mes2 (3 a) (Mes=2,4,6-trimethylphenyl) were synthesized by reactions of the corresponding disiloxane precursors Mes2Si(μ-O)2SiMes2 (2

1,2-disiladioxetanes: Structure, rearrangement, and reactivity

The low-temperature reaction of (E)-1,2-dimesityl-1,2-di-tert-butyldisilene (1a) with dioxygen gives (E)-1,2-dimesityl-1,2-di-tert-butyldisiladioxetane (2a), the structure of which has been established by X-ray crystallographic analysis. This result estab

Singlet oxygenation of oxadisiliranes. Syntheses and crystal structure of 1,2,3,4,5-trioxadisilolanes

Singlet oxygenation of 2,2,3,3-tetraarylyoxadisiliranes 1a-d gives the corresponding 1,2,4,3,5-trioxadisilolanes 2a-d, derivatives of a novel class of cyclic peroxides. The reaction mechanism is discussed in terms of possible peroxonium ion intermediate 6

Formation of a Disiloxirane in the Oxidation of 1,2-Dimesityl-1,2-di-t-butyldisilaethylene

Reaction of trans-1,2-di-t-butyl-1,2-dimesityldisilaethylene in solution with dioxygen at -78 deg C produces the disiloxirane (7) and a compound believed to be the 1,2-disiladioxetane (8a); the latter compound rearranges quantitatively to the known 1,3-cyclodisiloxane (5) above 0 deg C.