88589-59-7Relevant academic research and scientific papers
Molecular Scissors for Tailor-Made Modification of Siloxane Scaffolds
Bauer, Jonathan O.,Falk, Alexander,G?tz, Tobias
supporting information, (2021/12/09)
The controlled design of functional oligosiloxanes is an important topic in current research. A consecutive Si?O?Si bond cleavage/formation using siloxanes that are substituted with 1,2-diaminobenzene derivatives acting as molecular scissors is presented.
The electrochemistry of tetramesityldisilene, Mes2Si=SiMes2
Zhang, Zeng-Rong,Becker, James Y.,West, Robert C.
, p. 2719 - 2720 (2007/10/03)
The outcome of the controlled potential oxidation and reduction of a disilene, tetramesityldisilene (TMDS), indicates that the main silicon containing products involve only one silicon atom and have the general structure Mes2SiX(Y), X and Y being H, OH or F.
Reactions of Oxasilacyclopropane. Generation of Silanediyl by Photo and Thermal Induced Cycloelimination
Ando, Wataru,Hamada, Yoshitaka,Sekiguchi, Akira
, p. 952 - 954 (2007/10/02)
Dimesitylsilanediyl was generated from photolysis and pyrolysis of the oxasilacyclopropane (1) via a 2 + 1> cycloelimination reaction.
