845513-03-3Relevant articles and documents
Total synthesis of gambierol: Subunit coupling and completion
Johnson, Henry W. B.,Majumder, Utpal,Rainier, Jon D.
, p. 1747 - 1753 (2008/02/02)
The preceding manuscript detailed our synthesis of the gambierol A-C and F-H ring precursors. Reported herein is a description of the coupling of the two precursors and the conversion of the coupled material into gambierol. Coupling of the subunits involv
The total synthesis of gambierol
Johnson, Henry W. B.,Majumder, Utpal,Rainier, Jon D.
, p. 848 - 849 (2007/10/03)
This communication describes the total synthesis of the marine polyether toxin, gambierol. This work couples our iterative C-glycoside/enol ether-olefin metathesis strategy to the subunits with a unique olefin metathesis/carbonyl olefination reaction to bring the subunits together. Copyright