84553-34-4Relevant academic research and scientific papers
Mecanisme d'acetolyse d'esters d'enol styreniques
Montheard, Jean-Pierre,Camps, Marcel,Chatzopoulos, Michel,Benzaid, Ahmed
, p. 109 - 116 (2007/10/02)
We have studied the reaction of enol esters in acidic media: wherein Z = H, CH3, CH2Cl, CHCl2 and CCl3.The raction is first order.Log kex = α H'0 + β (H'0 = acidity function of Hammett) with α-1.A general acid catalysis is observed.Following a discussion of possible SN, AAC2 and ASE2 mechanisms, we propose an ASE2 mechanism for this reaction.
