845620-16-8Relevant articles and documents
Decarboxylative Claisen rearrangement reactions of allylic tosylmalonate esters
Craig, Donald,Grellepois, Fabienne
, p. 463 - 465 (2005)
(Chemical Equation Presented) Two different combinations of silylating agent and base are used for one-pot [3,3]-sigmatropic rearrangement- decarboxylation reactions of tosylmalonic mono(allylic) esters under mild conditions, providing the products of formal regiospecific allylation of methyl tosylacetate at the more substituted allylic terminus.