845646-12-0Relevant academic research and scientific papers
The first example of magnesium carbenoid 1,3-CH insertion reaction: A novel method for synthesis of cyclopropanes from 1-chloroalkyl phenyl sulfoxides in high yields
Satoh, Tsuyoshi,Musashi, Jun,Kondo, Atsushi
, p. 599 - 602 (2007/10/03)
Treatment of 1-chloroalkyl phenyl sulfoxides having a geminal methyl group or a geminal benzyl group at the 2-position in THF at -78°C with isopropylmagnesium chloride gave magnesium carbenoids. Carbenoid 1,3-CH insertion reaction of the magnesium carbeno
