84565-58-2Relevant academic research and scientific papers
CHBr3/TiCl4/Mg as an unusual nucleophilic CBr 2 carbenoid: Effective and chemoselective dibromomethylenation of aldehydes and ketones
Bhorge, Yeshwant Ramchandra,Chang, Cheng-Ta,Chang, Su-Haur,Yan, Tu-Hsin
experimental part, p. 4805 - 4810 (2012/10/08)
We report that instead of using CBr4, CHBr3 can serve as a highly nucleophilic dibromomethylene carbenoid in chemoselective carbonyl dibromomethylenation. Successful application of the dibromomethylenation to various carbonyl compoun
A SIMPLE ROUTE TO 3-(DIHALOMETHYLENE)CYCLO-ALKENES
Baird, Mark S.,Slowey, Paul D.
, p. 3795 - 3796 (2007/10/02)
Thermolysis of a number of bicyclic trihalocyclopropanes (1;X,Y=halogen) in the presence of quinoline leads either to 3-(dihalomethylene)cyclo-alkenes (8,9,10) with loss of halogen X or to ring expanded 1,2-dihalocycloalka-1,3-dienes (11,13) with loss of halogen Y, depending on ring size and on the nature of the halogen.
