845784-36-3

Upstream product

• 250284-80-1 2,6-dibromo-4-(2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-phenol 
• 77251-51-5 Bis-(2-benzyloxy-5-formyl-phenyl)-iodonium; bromide 
• 705932-33-8 4-benzyloxy-3-[2,6-dibromo-4-(2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-phenoxy]-benzaldehyde 
• 108-59-8 malonic acid dimethyl ester 

Downstream Products

• 845784-37-4 2-{4-benzyloxy-3-[2,6-dibromo-4-(2,2-dimethyl-[1,3]dioxolan-4-ylmethyl)-phenoxy]-benzyl}-malonic acid dimethyl ester 
• 845784-48-7 2-[(E)-Benzyloxyimino]-3-[4-(5-{2-[(E)-benzyloxyimino]-2-methoxycarbonyl-ethyl}-2-hydroxy-phenoxy)-3,5-dibromo-phenyl]-propionic acid 
• 845784-49-8 2-[(E)-Benzyloxyimino]-3-[4-(5-{2-[(E)-benzyloxyimino]-2-methoxycarbonyl-ethyl}-3-bromo-2-hydroxy-phenoxy)-3,5-dibromo-phenyl]-propionic acid 
• 845784-44-3 3-[4-Benzyloxy-3-(4-{2-[(E)-benzyloxyimino]-3-hydroxy-propyl}-2,6-dibromo-phenoxy)-phenyl]-2-[(E)-benzyloxyimino]-propionic acid methyl ester 
• 845784-45-4 3-[4-Benzyloxy-3-(4-{2-[(Z)-benzyloxyimino]-3-hydroxy-propyl}-2,6-dibromo-phenoxy)-phenyl]-2-[(E)-benzyloxyimino]-propionic acid methyl ester 
• 845784-47-6 3-[4-(2-Benzyloxy-5-{2-[(E)-benzyloxyimino]-2-methoxycarbonyl-ethyl}-phenoxy)-3,5-dibromo-phenyl]-2-[(E)-benzyloxyimino]-propionic acid 
• 845784-46-5 3-[4-(2-Benzyloxy-5-{2-[(E)-benzyloxyimino]-2-methoxycarbonyl-ethyl}-phenoxy)-3,5-dibromo-phenyl]-2-[(Z)-benzyloxyimino]-propionic acid 
• 845784-31-8 C₄₈H₃₉Br₅N₄O₈ 
• 845784-32-9 C₄₈H₃₉Br₅N₄O₈ 
• 845784-29-4 2-[(E)-Benzyloxyimino]-3-(3-{4-[2-[(E)-benzyloxyimino]-2-(2-{3-[2-bromo-4-(2-tert-butoxycarbonylamino-ethyl)-phenoxy]-4-hydroxy-phenyl}-ethylcarbamoyl)-ethyl]-2,6-dibromo-phenoxy}-5-bromo-4-hydroxy-phenyl)-propionic acid methyl ester 
• 845784-77-2 2-[(E)-Benzyloxyimino]-3-(3-{4-[2-[(E)-benzyloxyimino]-2-(2-{3-[2,6-dibromo-4-(2-tert-butoxycarbonylamino-ethyl)-phenoxy]-4-hydroxy-phenyl}-ethylcarbamoyl)-ethyl]-2,6-dibromo-phenoxy}-5-bromo-4-hydroxy-phenyl)-propionic acid methyl ester 
• 845784-30-7 2-[(E)-Benzyloxyimino]-3-(3-{4-[2-[(E)-benzyloxyimino]-2-(2-{3-bromo-5-[2-bromo-4-(2-tert-butoxycarbonylamino-ethyl)-phenoxy]-4-hydroxy-phenyl}-ethylcarbamoyl)-ethyl]-2,6-dibromo-phenoxy}-5-bromo-4-hydroxy-phenyl)-propionic acid methyl ester 

Relevant academic research and scientific papers

A general method for the synthesis of bastaranes and isobastaranes: First total synthesis of bastadins 5, 10, 12, 16, 20, and 21

A general strategy for the synthesis of twenty naturally occurring bastadins (all but bastadin 3) is presented. A key retrosynthetic disconnection of the two amide bonds, common in all target molecules, bisects the macrocyclic core into two diaryl ether f