845817-30-3

Upstream product

• 845817-23-4 1,2,3,4-tetradeoxy-4-{hydroxy[(1S)-1-phenylbut-3-enyl]amino}-5,6-O-(1-methylethylidene)-D-ribo-hept-1-enitol 
• 108-24-7 acetic anhydride 
• 444911-56-2 (3aR,4R,6aR)-tetrahydro-2,2-dimethyl-N-(phenylmethylene)furo[3,4-d]-1,3-dioxol-4-amine N-oxide 

Downstream Products

• 845817-32-5 (2S,7S)-2-[(4S,5R)-5-(hydroxymethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]-7-phenyl-2,3,6,7-tetrahydro-1H-azepin-1-ol 
• 845817-33-6 {(4R,5S)-2,2-dimethyl-5-[(2S,7S)-7-phenyl-2,3,6,7-tetrahydro-1H-azepin-2-yl]-1,3-dioxolan-4-yl}methanol 
• 845817-34-7 (3aR,6S,10aS,10bS)-2,2-dimethyl-6-phenyl-3a,6,7,10,10a,10b-hexahydro-4H-[1,3]dioxolo[3,4]pyrrolo[1,2-a]azepine 
• 845817-31-4 {(4R,5S)-5-[(2S,7S)-1-(acetyloxy)-7-phenyl-2,3,6,7-tetrahydro-1H-azepin-2-yl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol 

Relevant academic research and scientific papers

Double addition of Grignard reagents to N-glycosyl nitrones: A new tool for the construction of enantiopure azaheterocycles

(Chemical Equation Presented) C-Phenyl-N-erythrosylnitrone 3 behaves as a C1,C1′ bis-electrophile, undergoing a double addition of Grignard reagents in a domino fashion to afford acyclic hydroxylamines 4. The reaction proceeds at 0°C with variable degrees