845963-02-2

Basic information

• Product Name: Cp₂Ti[2,6-dimethylphenoxide]
• CAS NO: 845963-02-2
• Molecular Weight: 299.228
• Mol File: 845963-02-2.mol

Chemical Properties

• CAS DataBase Reference: Cp₂Ti[2,6-dimethylphenoxide](CAS DataBase Reference)
• NIST Chemistry Reference: Cp₂Ti[2,6-dimethylphenoxide](845963-02-2)
• EPA Substance Registry System: Cp₂Ti[2,6-dimethylphenoxide](845963-02-2)

Safety Data

• Hazardous Substances Data: 845963-02-2(Hazardous Substances Data)

Upstream product

• 24560-29-0 lithium 2,6-dimethylphenolate dimer 

Relevant articles and documents

The effect of titanium alkoxides in the synthesis of heterobimetallic complexes by titanocene(III) alkoxide-induced metal-metal bond cleavage of metal carbonyl dimers

A series of titanocene(III) alkoxides L2Ti(III)OR where L = Cp, R = Et(1b), tBu(1a), 2,6-Me2C6H 3(1c), 2,6-tBu2-4-Me-C6H 2(1d), or L = Cp*, R = Me(2e), tBu(2a), Ph(2f) was synthesized and subjected to reaction with [CpM(CO)3]2 [M = Mo, W], [CpRu(CO)2]2, and Co2(CO) 8. The Ti(III) precursors 1a, 1c, 2a, 2e, and 2f reacted with [CpM(CO)3]2 [M = Mo, W] to form heterobimetallic complexes L2Ti(OR)(μ-OC)(CO)2MCp [M = Mo, W], of which Ti and M are linked by an isocarbonyl bridge. Reactions of these Ti(III) complexes with Co2(CO)8 resulted in formation of Ti-Co1 heterobimetallic complexes, Cp2*Ti(OtBu)(μ-OC) Co(CO)3 from 2a, 2e, or 2f, or Ti-Co3 tetrametallic complexes, Cp2Ti(OtBu)(μ-OC)Co3(CO) 9 from 1a, 1b, or 1c. The products were characterized by NMR, IR, and X-ray crystallography. Reaction mechanisms were proposed from these results, in particular, from steric/electronic effects of titanium alkoxides.