84606-53-1Relevant academic research and scientific papers
Base Induced 1,2-Hydride Shifts from Silicon to Carbon: "Anomalous" Substitution reactions with (Halomethyl)diorganosilanes
Tacke, Reinhold,Lange, Hartwig,Attar-Bashi, Moayad T.
, p. 1946 - 1951 (2007/10/02)
(C6H5)2Si(H)CH2X (1a: X = Cl; 1b: X = I) and C6H5(CH3)Si(H)CH2Cl (10) react with LiOCH2CH2N(CH3)2 (2b) to give the alkoxysilanes (C6H5)2Si(CH3)OCH2CH2N(CH3)2 (5) and C6H5(CH3)2SiOCH2CH2N(CH3)2 (12), respectively.The formation of these unexpected reaction
