84615-18-9Relevant academic research and scientific papers
EFFECT OF STRUCTURE ON THE KINETICS AND MECHANISM OF THE ACID-CATALYZED DECOMPOSITION OF N-NITROBENZENESULFONAMIDES
Drozdova, O. A.,Astrat'ev, A. A.,Kuznetsov, L. L.,Selivanov, V. F.
, p. 2063 - 2067 (2007/10/02)
The decomposition rate of a series of ring-substituted N-nitrobenzenesulfonamides in aqueous sulfuric acid was measure by a spectrophotometric method.Decomposition of the compounds takes place both by the cleavage of the N-S bond to form the corresponding sulfonic acid, nitrous oxide, and water and by denitration.In crease in the electronegativity of the substituent in the aromatic ring promotes the denitration reaction.
