84675-17-2Relevant academic research and scientific papers
Synthesis of α-Fluorovinylphosphonates
Blackburn, G. Michael,Parratt, Martin J.
, p. 1417 - 1424 (2007/10/02)
A new general synthesis of α-fluorovinylphosphonates is provided by a Wadsworth-Emmons condensation of tetra-alkyl fluoromethylenebisphosphonates (1) with aldehydes and ketones.The reaction shows useful stereoselectivity favouring the less-hindered alkene
The Synthesis of α-Fluorovinylphosphonates
Blackburn, G. Michael,Parratt, Martin J.
, p. 1270 - 1271 (2007/10/02)
A general synthesis of α-fluorovinylphosphonates results from Wadsworth-Emmons condensation of tetra-alkyl fluoromethylenebisphosphonates with aldehydes and ketones with stereoselectivity favouring the less hindered product which can be reduced to give α-
