847205-40-7Relevant academic research and scientific papers
Oligonucleosides with a nucleobase-including backbone: Part 12 - Synthesis of mixed ethynylene-linked uridine- and adenosine-derived tetramers
Eppacher, Simon,Bhardwaj, Punit Kumar,Bernet, Bruno,Gala, Jose Luis Bravo,Knoepfel, Thomas,Vasella, Andrea
, p. 2969 - 2986 (2007/10/03)
In contradistinction to the corresponding Grignard reagent, bis[(trimethylsilyl)ethynyl]zinc reacted with the 5′-oxoadenosine 3 diastereoselectively to the β-D-allo-hept-6-ynofuranosyladenine 5. Lithiation/iodination of the monomeric propargyl alcohol 5 a
