84773-09-1Relevant articles and documents
Synthesis and structure of selected quaternary N-(1,4-anhydro-5-deoxy-2,3- O-isopropylidene-D,L-ribitol-5-yl)ammonium salts
Skorupa, Eugenia,Dmochowska, Barbara,Pellowska-Januszek, Lucyna,Wojnowski, Wies?aw,Chojnacki, Jaros?aw,Wi?niewski, Andrzej
, p. 2355 - 2362 (2007/10/03)
The syntheses have been developed for quaternary N-(1,4-anhydro-5-deoxy-2, 3-O-isopropylidene-d,l-ribitol-5-yl)ammonium salts derived from five aromatic amines, pyridine, 2-methylpyridine, 3-carbamoylpyridine, 4-(N,N-dimethylamino) pyridine, and quinoline, as well as two tertiary aliphatic amines, trimethylamine and triethylamine. Reactions of 1,4-anhydro-2,3-O-isopropylidene- 5-O-tosyl-d,l-ribitol with tri-n-propylamine and tri-n-butylamine were unsuccessful. The products were identified on the basis of their 1H and 13C NMR spectra. The structure of N-(1,4-anhydro-5-deoxy-2,3-O- isopropylidene-d,l-ribitol-5-yl)trimethylammonium tosylate was additionally elucidated by X-ray diffractometry.
THE ISOPROPYLIDENATION OF D-RIBOSE DIETHYL DITHIOACETAL AND RIBITOL. A NEW SYNTHESIS OF α- AND β-D-RIBOFURANOSYLETHYNE via 2,3:4,5-DI-O-ISOPROPYLIDENE-aldehydo-D-RIBOSE
Aslani-Shotorbani, Gaffar,Buchanan, J. Grant,Edgar, Alan R.,Shahidi, Parvin K.
, p. 37 - 52 (2007/10/02)
The reaction of D-ribose diethyl dithioacetal with acetone and sulphuric acid in the presence of anhydrous copper sulphate gives the 2,3:4,5-di-O-isopropylidene derivative 14 (40percent) and the isomeric 2,5:3,4-di-O-isopropylidene acetal 17 (40percent),