84782-65-0Relevant academic research and scientific papers
A HIGHLY SELECTIVE ONE-CARBON RING ENLARGEMENT REACTION DIRECTED BY SILICON
Tanino, Keiji,Katoh, Tetsuya,Kuwajima, Isao
, p. 1815 - 1818 (2007/10/02)
On treatment with dichloroaluminium phenoxide, 1-(trimethylsilyl)methylcycloalkanecarbaldehydes undergo selective rearrangement of ring carbons to give the corresponding one-carbon ring enlarged 2-(trimethylsilyl)methylcycloalkanones in excellent yields.
New Rearrangement of Phenylseleno- and Trimethylsilylmethyl Groups in 2-Hydroxy-3-trimethylsilylpropyl Selenides
Nishiyama, Hisao,Kitajima, Toshio,Yamamoto, Akiko,Itoh, Kenji
, p. 1232 - 1233 (2007/10/02)
2-Hydroxy-3-trimethylsilylpropyl selenides, readily prepared by the reaction of α-phenylselenoaldehydes and trimethylsilylmethyl-lithium, are transformed into primary allylic selenides and β-trimethylsilylpropanals by acid-catalysed dehydroxysilylation accompanied by a phenylseleno-shift, and by silver-induced rearrangement of the trimethylsilylmethyl group, respectively.
