847833-39-0Relevant academic research and scientific papers
A synthesis of 5-hydroxysedamine using hydroformylation
Bates, Roderick W.,Aslam, Nur Filza Bte Mohamed,Tang, Chi H.,Simon, Oliver
, p. 2134 - 2140 (2014/03/21)
A synthesis of 5-hydroxysedamine, a Sedum alkaloid, has been completed using N,O-heterocycle chemistry to establish the aminoalcohol structure, hydroformylation to form the piperidine ring and diastereoselective dihydroxylation to introduce the 5-hydroxy group.
Influence of hydroxylamine conformation on stereocontrol in Pd-catalyzed isoxazolidine-forming reactions
Lernen, Georgia S.,Giampietro, Natalie C.,Hay, Michael B.,Wolfe, John P.
supporting information; experimental part, p. 2533 - 2540 (2009/08/07)
Palladium-catalyzed carboamination reactions between N-Boc-O-(but-3-enyl) hydroxylamine derivatives and aryl or alkenyl bromides afford cis-3,5- and trans-4,5-disubstituted isoxazolidines in good yield with up to >20:1 dr. The diastereoselectivity observe
