847834-43-9

Basic information

• Product Name: 4H-1,2-Oxazine-6-methanol, 5,6-dihydro-3-phenyl-
• CAS NO: 847834-43-9
• Molecular Formula: C11H13NO2
• Molecular Weight: 191.23
• Mol File: 847834-43-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4H-1,2-Oxazine-6-methanol, 5,6-dihydro-3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 4H-1,2-Oxazine-6-methanol, 5,6-dihydro-3-phenyl-(847834-43-9)
• EPA Substance Registry System: 4H-1,2-Oxazine-6-methanol, 5,6-dihydro-3-phenyl-(847834-43-9)

Safety Data

• Hazardous Substances Data: 847834-43-9(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 59239-04-2 1-phenyl-4-penten-1-one oxime 
• 102632-99-5 1-phenyl-4-penten-1-ol 
• 90466-95-8 1-phenyl-4,5-epoxypentan-1-one 
• 3240-29-7 1-Phenylpent-4-en-1-one 
• 947493-86-9 C₁₁H₁₃NO₂ 
• 10341-75-0 (E)-1-phenylethanone oxime 
• 3132-64-7 1,2-Epoxy-3-bromopropane 
• 613-91-2 acetophenone oxime 

Relevant articles and documents

Green organocatalytic synthesis of isoxazolines via a one-pot oxidation of allyloximes

A green, sustainable, organocatalytic, and efficient synthesis of isoxazolines from allyloximes was developed. A 2,2,2-trifluoroacetophenone-catalyzed oxidation of allyloximes, utilizing H2O2 as the green oxidant, was taken advantage of in order to introduce a cheap and environmentally friendly protocol for the synthesis of substituted isoxazolines. A variety of substitution patterns, both aromatic and aliphatic moieties, are well tolerated, leading to isoxazolines in moderate to excellent yields.

One-pot cyclizations of dilithiated oximes and hydrazones with epibromohydrin. Efficient synthesis of 6-hydroxymethyl-5,6-dihydro-4H-1,2- oxazines and oxazolo[3,4-b]pyridazin-7-ones

The one-pot cyclization of dilithiated oximes with epibromohydrin provided a convenient and regioselective approach to 6-hydroxymethyl-5,6-dihydro-4H-1,2- oxazines. The reaction of the latter with phosphorus tribromide resulted in a Beckmann rearrangement