84784-85-0Relevant articles and documents
Pentacoordinate vs. Tetracoordinate complexation for alkoxycarbonyl compounds with dialkylboron triflates and trifluoroacetates?
Ooi, Takashi,Uraguchi, Daisuke,Maruoka, Keiji
, p. 8105 - 8108 (1998)
The implication of hitherto unknown pentacoordinate complex formation for alkoxycarbonyl compounds with Et2BX (X =OTf, OCOCF3) is presented by several reduction/allylation experiments and low-temperature 13C, 11
Stereoselective Reduction of α-Methyl-β-hydroxy Ketones with Zinc Borohydride
Nakata, Tadashi,Tani, Yoichiro,Hatozaki, Masayoshi,Oishi, Takeshi
, p. 1411 - 1415 (2007/10/02)
Zinc borohydride reduction of α-methyl-β-hydroxy ketones 3 produced the erythro-2-methyl-1,3-glycol derivatives 4 with high stereoselectivity.The selectivity was particularly high when an olefinic group was conjugated to the carbonyl group.Reduction of th