Pentacoordinate vs. Tetracoordinate complexation for alkoxycarbonyl compounds with dialkylboron triflates and trifluoroacetates?

DOI: 10.1016/S0040-4039(98)01798-5

Source and publish data:

Tetrahedron Letters p. 8105 - 8108 (1998)

Update date:2022-07-29

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Authors:

Ooi, Takashi

Uraguchi, Daisuke

Maruoka, Keiji

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Article abstract of DOI:10.1016/S0040-4039(98)01798-5

The implication of hitherto unknown pentacoordinate complex formation for alkoxycarbonyl compounds with Et₂BX (X =OTf, OCOCF₃) is presented by several reduction/allylation experiments and low-temperature ¹³C, ¹¹

Full text of DOI:10.1016/S0040-4039(98)01798-5

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