848094-05-3Relevant academic research and scientific papers
Syntheses and X-ray diffraction studies of half-sandwich hydridosilyl complexes of ruthenium
Osipov, Alexander L.,Gerdov, Sergei M.,Kuzmina, Lyudmila G.,Howard, Judith A. K.,Nikonov, Georgii I.
, p. 587 - 602 (2005)
A series of a half-sandwich trihydrides of ruthenium was synthesized and investigated using x-ray diffraction. The reaction of ruthenium trihydrides with chlorosilanes occurred in complex manner and resulted in various products. With more acidic silanes, HSiCl2Me and HSiCl3, the formation of the Ru-Cl bond becomes reaction route. Results show that Ruthenium compound can support the occurrence of H-Si interaction in its silyl hydride derivatives.
