84812-55-5Relevant academic research and scientific papers
Reactivity of cis-Bis(dimethylphenylsilyl)bis(phosphine)platinum Complexes toward Unsaturated Compounds Relevant to Double Silylation
Kobayashi, Toshi-aki,Hayashi, Teruyuki,Yamashita, Hiroshi,Tanaka, Masato
, p. 467 - 470 (2007/10/02)
The reaction of phenylacetylene, tolane, or isoprene with cis-bis(dimethylphenylsilyl)bis(methyldiphenylphosphine)platinum readily took place to result in 1,2- or 1,4- double silylation, respectively.Ethylene also underwent double silylation with the platinum complex, but styrene selectively gave E-2-(dimethylphenylsilyl)styrene.
