84836-46-4Relevant academic research and scientific papers
Chemical and Electrochemical Oxidation of O,O,O-Trisubstituted Phosphorothioates and Triphenylphosphine Sulfide
Blankespoor, Ronald L.,Doyle, Michael P.,Smith, Daniel J.,Dyke, David A. Van,Waldyke, Michael J.
, p. 1176 - 1179 (1983)
The chemical and electrochemical oxidation of O,O,O-trialkyl phosphorothioates and triphenylphosphine sulfide are reported.Reaction of the latter compound with nitrosonium tetrafluoroborate produces a dimeric dication that is relatively stable in acetonitrile solution but rapidly decomposes upon attempted isolation.Electrooxidation of triphenylphosphine sulfide similarly gives a dimeric dication via the intermediacy of a dimer cation radical.Reaction of O,O,O-triethyl phosphorothioate with nitrosonium tetrafluoroborate produces bis(diethylphosphoryl)disulfide and the N-ethylacetonitrilium ion whereas its oxidation at the surface of platinum results in the formation of the N-ethylacetonitrilium ion and products that are not identified.
