848397-71-7

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 158716-07-5 phenyl 3-O-benzyl-4,6-O-benzylidene-1-thio-α-D-mannopyranoside 

Downstream Products

• 863297-03-4 (2R,4aR,6R,7R,8S,8aR)-6-Azido-8-benzyloxy-2-phenyl-7-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 863297-04-5 (2R,4aR,6S,7R,8S,8aR)-6-Azido-8-benzyloxy-2-phenyl-7-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine 

Relevant academic research and scientific papers

Glycosyl azides of sugar 2-sulfonic acids

Phenyl and trityl 2-O-sulfonyl-1-thio-α-d-manno- and β-d-glucopyranosides were reacted with sodium azide to yield 2-S-phenyl or 2-S-trityl-d-gluco- and d-mannopyranosyl azides, respectively. Usually, both anomers were formed in approximately equal amounts

Disarming, non-participating 2-O-protecting groups in manno- and rhamnopyranosylation: Scope and limitations of sulfonates, vinylogous esters, phosphates, cyanates, and nitrates

A series of d-mannopyranosyl and l-rhamnopyranosyl thioglycosides protected with electron-withdrawing, non-participating protecting groups on O-2 have been prepared and investigated for their potential as β-glycosyl donors. Both α- and β-thioglycosides we