848737-66-6

Basic information

• Product Name: [Ag(MeCN)₂][B{C₆H₃(CF₃)₂-3,5}₄]
• Synonyms: [Ag(MeCN)₂][B{C₆H₃(CF₃)₂-3,5}₄]
• CAS NO: 848737-66-6
• Molecular Weight: 1053.19
• Mol File: 848737-66-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ag(MeCN)₂][B{C₆H₃(CF₃)₂-3,5}₄](CAS DataBase Reference)
• NIST Chemistry Reference: [Ag(MeCN)₂][B{C₆H₃(CF₃)₂-3,5}₄](848737-66-6)
• EPA Substance Registry System: [Ag(MeCN)₂][B{C₆H₃(CF₃)₂-3,5}₄](848737-66-6)

Safety Data

• Hazardous Substances Data: 848737-66-6(Hazardous Substances Data)

Upstream product

• 75-05-8 acetonitrile 
• 105560-52-9 potassium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate 
• 160298-76-0 silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate 

Relevant articles and documents

Organonitrile ligated silver complexes with perfluorinated weakly coordinating anions and their catalytic application for coupling reactions

Homogeneous catalytic processes mediated by silver(I) complexes are relatively rare. This work describes the synthesis and characterization of acetonitrile ligated silver salts with three weakly coordinating anions [B(C6F5)4]- [B{C6H 3(CF3)2}4]- and [(C 6F5)3B-C3H4N 2-B(C6F5)3]-. The silver cation is coordinated either by four or by two acetonitrile ligands. All examined Ag(I) complexes show catalytic activity in coupling reactions of terminal alkynes with aldehydes and amines. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2005.