848749-43-9Relevant academic research and scientific papers
A new class of organic donor-acceptor molecules with large third-order optical nonlinearities
Michinobu, Tsuyoshi,May, Joshua C.,Lim, Jin H.,Boudon, Corinne,Gisselbrecht, Jean-Paul,Seiler, Paul,Gross, Maurice,Biaggio, Ivan,Diederich, Francois
, p. 737 - 739 (2005)
Donor-acceptor molecules with 4-(dimethylamino)phenyl donor and 1,1,4,4-tetracyanobuta-1,3-diene acceptor moieties are readily prepared by short, high-yielding routes. The quite small chromophores are characterised by X-ray crystallography and feature int
Near-Infrared Fluorescent Probes with Rotatable Polyacetylene Chains for the Detection of Amyloid-β Plaques
Zhang, Longfei,Gong, Xin,Tian, Chuan,Fu, Hualong,Tan, Hongwei,Dai, Jiapei,Cui, Mengchao
, p. 497 - 506 (2021/01/26)
The plaques of accumulated β-amyloid (Aβ) in the parenchymal brain are accepted as an important biomarker for the early diagnosis of Alzheimer's disease (AD). Many near-infrared (NIR) probes, which were based on the D-π-A structure and bridged by conjugat
Multipodal arrangement of push-pull chromophores: a fundamental parameter affecting their electronic and optical properties
Klikar,Kityk,Kulwas,Mikysek,Pytela,Bure?
supporting information, p. 1459 - 1472 (2017/02/23)
A series of model push-pull molecules with linear, quadrupolar, and tripodal arrangements, a varyingly substituted amino donor, two acceptors, and a partially extended π-system has been prepared. Two peripheral electron acceptors, namely N,N′-dibutylbarbituric acid and dicyanovinyl, were employed. The fundamental properties of 24 push-pull chromophores were investigated by differential scanning calorimetry, electrochemistry, one-photon absorption spectroscopy, photoinduced piezooptics, and were supported by DFT calculations. Thorough structure-property relationships were elucidated, while a significant influence of the structural arrangement/branching on the electronic and optical properties has been revealed. The fundamental optoelectronic properties of push-pull molecules are affected by their arrangement (linear/quadrupolar/tripodal), the peripheral acceptor attached, extension and planarization of the π-system, and also by the type of auxiliary N-substituent.
