848819-65-8Relevant academic research and scientific papers
Observation of co-existence of 'face-on' and 'edge-on' stacking styles in a porphyrin monolayer
Zhou, Yunshen,Wang, Bing,Zhu, Manzhou,Hou
, p. 140 - 145 (2005)
We report a direct observation adopting 'face-on' and 'edge-on' stacking styles in monolayer of a novel porphyrin derivative on highly ordered pyrolytic graphite (HOPG) using scanning tunneling microscope (STM). The porphyrin derivative, 5-hydroxyphenyl-10, 15, 20-trikis(4-dodecyloxyphenyl) porphyrinatozinc(II) (ZnDPPOH) is synthesized and assembled on HOPG. In the STM images, we observed two kinds of ordered domains. One consists of ZnDPPOH dimmers, adopting 'face-on' stacking style, the other exhibits a segmented columnar structure, like piled-up 'armchairs', lying down on the substrate, adopting an 'edge-on' stacking style. In the latter case, the conjugated and highly delocalized π-systems play key roles in stabilizing the monolayer.
