24083-19-0Relevant articles and documents
Giant porphyrin disks: Control of their self-assembly at liquid-solid interfaces through metal-ligand interactions
Lensen, Marga C.,Elemans, Johannes A. A. W.,Van Dingenen, Sandra J. T.,Gerritsen, Jan W.,Speller, Sylvia,Rowan, Alan E.,Nolte, Roeland J. M.
, p. 7948 - 7956 (2007)
The synthesis and self-assembly behaviour of porphyrin dodecamers 1H 2 and Zn-1, which consist of twelve porphyrins that are covalently attached to a central aromatic core, is described. According to STM, 1D and 2D NMR studies, and molecular mo
Synthesis and determination of thermotropic liquid crystalline behavior of cinnamaldehyde-based molecules with two schiff base linking units
Jamain, Zuhair,Khairuddean, Melati,Omar, Nor Faizawani
, (2020)
A series of liquid crystal molecules with two Schiff base linking units and a cinnamaldehyde core with different terminal groups were synthesized and characterized. The intermediates of 4-heptyloxybenzaldehyde (1a) and 4-dodeyloxybenzaldehyde (1b) were synthesized through the alkylation of 4-hydroxybenzaldehyde with a series of bromoalkane. A condensation reaction of cinnamaldehyde, 1,4-phenylenediamine and a series of substituted benzaldehydes with different terminal groups such as bromo, chloro, hydroxy, cinnamaldehyde, hydrogen, methoxy, heptyloxy and dodecyloxy produced a series of new cinnamaldehyde-based compounds, 2-9, respectively. All these compounds were characterized using Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, and CHN elemental analysis. The liquid crystal properties of these compounds were determined using polarized optical microscopy (POM), and their transitions were further confirmed using differential scanning calorimetry (DSC). Compounds with chloro, bromo, methoxy, heptyloxy, and dodecyloxy substituents are mesogenic compounds with nematic phase behavior. However, the other compounds were found to be non-mesogenic without any mesophase transitions. The structure-property relationship was investigated in order to study the effect of different terminal groups and Schiff base linking units on the liquid crystalline behavior of these compounds.
Mesogenic complementary absorbing dyads based on porphyrin and perylene units
Kong, Xiangfei,Gong, Hongkang,Dai, Shengping,Yao, Wei,Mu, Linping,Zhang, Shufen,Wang, Guixia
, p. 221 - 232 (2018)
Five novel dyads, consisting of a tetraphenylporphyrine unit connected to a perylene monoimide diester unit via a flexible bridge-CONH-(CH2)n-(n = 4, 6, 8, 10 and 12), have been synthesized. Their structures were characterized by 13C and 1H nuclear magnet
An amphiphilic B,O-chelated aza-BODIPY dye: synthesis, pH-sensitivity, and aggregation behaviour in a H2O/DMSO mixed solvent
Chen, Zhijian,Lei, Bin,Pan, Hongfei,Ren, Xiang-Kui,Zhang, Yongjie
, p. 6108 - 6114 (2021)
A novel amphiphilic B,O-chelated azadipyrromethene (aza-BODIPY) dye, containing hydrophobic dodecyloxy groups and hydrophilic tetraethylene glycol (TEG) chains, was synthesized and characterized by NMR, HRMS, Vis/NIR absorption and fluorescence spectrosco
Near-infrared fluorescent amphiphilic Aza-BODIPY dye: Synthesis, solvatochromic properties, and selective detection of Cu2+
Chen, Yuanfang,Chen, Zhijian,Pan, Hongfei,Ren, Xiang-Kui,Wang, Houchen,Zhang, Yongjie,Zuo, Jiahe
, (2020)
A new amphiphilic near-infrared aza-BODIPY dye bearing both hydrophobic alkyl and hydrophilic oligo-ethylene glycol chains was synthesized by facile click reaction. By introducing the electron-donating N,N-disubstituted amino groups into the molecular str
Surfactant effect on titanium dioxide photosensitized oxidation of 4-dodecyloxybenzyl alcohol
Bettoni, Marta,Brinchi, Lucia,Del Giacco, Tiziana,Germani, Raimondo,Meniconi, Sara,Rol, Cesare,Sebastiani, Giovanni Vittorio
, p. 53 - 59 (2012)
The TiO2 photosensitized oxidation of 4-dodecyloxybenzyl alcohol (1), water insoluble, was investigated in aqueous surfactant solutions. A variety of surfactants of different charge type was used and in some cases the pH effect was investigated
Concentration and acid-base controllable fluorescence of a metallosupramolecular polymer
He, Lipeng,Liang, Jianjun,Cong, Yong,Chen, Xin,Bu, Weifeng
, p. 10841 - 10844 (2014)
A metallosupramolecular polymer (MP-Zn) bearing dibenzo-24-crown-8 (DB24C8) arms is constructed by coordinating Zn2+ with a conjugated bis-terpyridine ligand, which indicates concentration-dependent emissions from cyan to white to yellow. Succe
Helical polymer-anchored porphyrin nanorods
De Witte, Pieter A. J.,Castriciano, Mariangela,Cornelissen, Jeroen J. L. M.,Scolaro, Luigi Monsu,Nolte, Roeland J. M.,Rowan, Alan E.
, p. 1775 - 1781 (2003)
Well-defined arrays of porphyrins attached to a rigid polyisocyanide backbone have been synthesized and their physical and optical properties studied. The helical polymers are rigidified by an inter-side chain hydrogen-bonded network and have an average m
Metal-free C-H functionalization of pyrrolidine to pyrrolinium-based room temperature ionic liquid crystals
Mandal, Sumana,Gupta, Ravindra Kumar,Pathak, Suraj Kumar,Rao, D. S. Shankar,Prasad, S. Krishna,Ammathnadu Sudhakar, Achalkumar,Jana, Chandan K.
supporting information, p. 8064 - 8071 (2021/05/21)
The development of ionic liquid crystals (ILCs) using pyrrolidinium cation has received considerable interest due to their higher electrochemical stability. However, high charge density associated with low charge distribution in the fully saturated pyrrol
Aza-BODIPY molecular assembly at the liquid-solid interface driven by Br?F[sbnd]BF interactions
Xiao, Yuchuan,Cai, Fangjian,Peng, Xuan,Kang, Xiyuan,Lei, Peng,Li, Xin,Xu, Haijun,Xiao, Xunwen,Tu, Bin,Zeng, Qingdao
supporting information, p. 3566 - 3569 (2021/04/12)
In this work, two aza-BODIPY derivatives, 3,5-diphenyl-1,7-di(p-dodecyloxyphenyl)-aza-BODIPY (CJF) and 3,5-di(p-bromophenyl-1,7-di(p-dodecyloxyphenyl)-aza-BODIPY (2Br-CJF) acted as model molecules to form the self-assembly monolayers on the solid-liquid i
