849097-60-5Relevant academic research and scientific papers
Enantioselective friedel-crafts alkylations with benzoylhydrazones promoted by a simple strained silacycle reagent
Shirakawa, Seiji,Berger, Richard,Leighton, James L.
, p. 2858 - 2859 (2005)
The enantioselective Friedel-Crafts reaction of electron-rich arenes and heteroarenes with the benzoylhydrazone of isopropyl glyoxylate mediated by a simple chiral silane Lewis acid is described. The reactions are highly practical, as demonstrated by a la
SILACYCLE COMPOUNDS AND METHODS OF USE THEREOF
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Page/Page column 25; 26, (2010/11/08)
The present invention relates to a diastereomeric mixture of Silacycle Compounds and methods for using the diastereomeric mixture of Silacycle Compounds for stereoselective synthesis.
