849097-86-5

Upstream product

• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 41302-34-5 2-(methoxycarbonyl)cyclohexanone 
• 67-56-1 methanol 
• 1655-07-8 ethyl 2-oxocyclohexane carboxylate 

Downstream Products

• 849097-87-6 3-[1-(3,4-Dimethoxy-phenyl)-meth-(Z)-ylidene]-1-methyl-2-oxo-cyclohexanecarboxylic acid methyl ester 
• 849097-90-1 3-(3,4-dimethoxy-benzyl)-1-methyl-2-trifluoromethanesulfonyloxy-cyclohex-2-enecarboxylic acid methyl ester 
• 849097-91-2 3-(2-bromo-4,5-dimethoxy-benzyl)-1-methyl-2-trifluoromethanesulfonyloxy-cyclohex-2-enecarboxylic acid methyl ester 
• 849097-94-5 3-(4,5-dimethoxy-2-vinyl-benzyl)-1-methyl-2-trifluoromethanesulfonyloxy-cyclohex-2-enecarboxylic acid methyl ester 
• 849097-92-3 3-(2-bromo-4,5-dimethoxy-benzyl)-1-methyl-2-vinyl-cyclohex-2-enecarboxylic acid methyl ester 
• 849097-93-4 3-(4,5-dimethoxy-2-vinyl-benzyl)-1-methyl-2-oxo-cyclohexanecarboxylic acid methyl ester 
• 849097-89-8 3-(2-bromo-4,5-dimethoxy-benzyl)-1-methyl-2-oxo-cyclohexanecarboxylic acid methyl ester 
• 849097-88-7 3-(3,4-dimethoxy-benzyl)-1-methyl-2-oxo-cyclohexanecarboxylic acid methyl ester 

Relevant academic research and scientific papers

Intramolecular Heck reaction strategy for the synthesis of functionalised tetrahydroanthracenes: A facile formal total synthesis of the linear abietane diterpene, umbrosone

Rapid annulation employing an intramolecular Heck reaction yielded the functionalised 1,1,10-trimethyl-6-methoxy-1,2,3,4-tetrahydroanthracene 4a, a key intermediate for the linear diterpenoid quinone umbrosone (1), and the related compounds 4b-d. A simila