84918-79-6Relevant academic research and scientific papers
Fe-Catalysed oxidative C-H/N-H coupling between aldehydes and simple amides
Wang, Jing,Liu, Chao,Yuan, Jiwen,Lei, Aiwen
supporting information, p. 4736 - 4739 (2014/05/06)
A novel oxidative coupling of aldehydes with simple amides, most likely involving a radical process, was achieved through the use of an iron catalyst. Various amides were utilized as substrates to easily construct imides by coupling with aldehydes. A catalytic cycle involving the benzoyl halide intermediate is proposed based on our experimental results. This journal is the Partner Organisations 2014.
Reaction of Arenediazonium Salts with Nitriles in the Presence of Sodium Carboxylates. A Convenient Synthesis of Unsymmetrical N-Aryl Acyclic Imides
Kikukawa, Kiyoshi,Kono, Kiyoshi,Wada, Fumio,Matsuda, Tsutomu
, p. 3671 - 3672 (2007/10/02)
Reactions of arenediazonium tetrafluoroborates (ArN2BF4), acetonitrile and sodium carboxylates (RCOONa) gave N-acyl acetanilides (ArN(COR)COCH3) in moderate to good yields (Ar=Ph, 2-MeC6H4, 3-MeC6H4, 4-MeC6H4, 2,6-(Me)2C6H3; R=Et, i-Pr, t-Bu, Ph).Acrylonitrile and benzonitrile could be used in the reaction instead of acetonitrile.
