849201-64-5

Upstream product

• 849201-68-9 (4S,5S)-5-benzoyloxy-1,5-diphenyl-2-diphenylphosphinoyl-4-hydroxypentan-1-one 
• 335274-36-7 (1'S,2R,3R,5S)-3-Diphenylphosphinoyl-5-[phenyl(benzoyloxy)methyl]-2-phenyl-2-trimethylsilyloxytetrahydrofuran 
• 849201-69-0 (4S,5S)-5-benzoyloxy-1,5-diphenyl-4-diphenylphosphinyloxy-pentan-1-one 
• 849201-70-3 (2RS,4S,5S)-4,5-dihydroxy-1,5-diphenyl-2-diphenylphosphinoyl-pentan-1-one 
• 849201-71-4 (1'S,2'S,1''R)-{2'-[benzoyloxy(phenyl)methyl]cyclopropyl}(phenyl)methanone 

Relevant academic research and scientific papers

Asymmetric cyclopropane synthesis via phosphine oxide mediated cascade reactions

A silyloxy-THF has been converted into a cyclopropane containing three stereocentres as mixture of diastereoisomers. The mechanism of the reaction has been established and the source of stereochemical leakage proposed. An alternative stereospecific cascad