849201-68-9

Upstream product

• 230965-19-2 (1S,2S)-4-Diphenylphosphinoyl-1-phenylbutane-1,2-diol 
• 335274-36-7 (1'S,2R,3R,5S)-3-Diphenylphosphinoyl-5-[phenyl(benzoyloxy)methyl]-2-phenyl-2-trimethylsilyloxytetrahydrofuran 
• 335274-29-8 (1S,2S)-1,2-Bis(benzoyloxy)-4-diphenylphosphinoyl-1-phenylbutane 
• 98-88-4 benzoyl chloride 

Downstream Products

• 849201-64-5 (1'S,2'S,1''R)-{2'-[hydroxy(phenyl)methyl]cyclopropyl}(phenyl)methanone 
• 335274-41-4 (4S,5S)-2-Diphenylphosphinoyl-1,5-diphenylpentane-1,4,5-triol 

Relevant academic research and scientific papers

Asymmetric cyclopropane synthesis via phosphine oxide mediated cascade reactions

A silyloxy-THF has been converted into a cyclopropane containing three stereocentres as mixture of diastereoisomers. The mechanism of the reaction has been established and the source of stereochemical leakage proposed. An alternative stereospecific cascad

The chemistry of lithiated phosphine oxides: The stereoselective syntheses of alkene-4,5-diols

The synthesis of single enantiomers of (E)-1,5-diarylpentene-4,5-diols by elimination reaction was discussed. The stereochemistry was controlled by an asymmetric dihydroxylation, and a stereoselective reduction of a β-keto phosphine oxide. Results showed