849436-19-7Relevant academic research and scientific papers
Highly site- and enantioselective Cu-catalyzed allylic alkylation reactions with easily accessible vinylaluminum reagents
Lee, Yunmi,Akiyama, Katsuhiro,Gillingham, Dennis G.,Brown, M. Kevin,Hoveyda, Amir H.
, p. 446 - 447 (2008/09/20)
An efficient method for catalytic asymmetric allylic alkylation (AAA) of allylic phosphates with vinylaluminum reagents is reported. The vinylmetal reagents are prepared by reaction of commercially available DIBAL-H and a terminal alkyne. The resulting vi
Enantioselective ene reaction of cyclopentadiene and α,β-enals catalyzed by a diphenylprolinol silyl ether
Gotoh, Hiroaki,Masui, Ryouhei,Ogino, Hiroshi,Shoji, Mitsuru,Hayashi, Yujiro
, p. 6853 - 6856 (2007/10/03)
(Chemical Equation Presented) The opposite result: A diphenylprolinol silyl ether promotes an intermolecular enantioselective ene reaction of α,β-enals with cyclopentadiene. This is the first example of cyclopentadiene acting as the ene component, and not
