84958-32-7

Upstream product

• 593-60-2 Vinyl bromide 
• 2040-20-2 4-methoxyisobutyrophenone 
• 1826-67-1 vinyl magnesium bromide 
• 100-66-3 methoxybenzene 

Downstream Products

• 84958-10-1 2-(3-(4-methoxyphenyl)-4-methylpent-2-enyl)-2-methyl-cyclopentane-1,3-dione 
• 21550-01-6 1-(4'-methoxyphenyl)-4-methylpentan-1-one 

Relevant academic research and scientific papers

1,3-Alkyl Transposition in Allylic Alcohols Enabled by Proton-Coupled Electron Transfer

A method is described for the isomerization of acyclic allylic alcohols into β-functionalized ketones via 1,3-alkyl transposition. This reaction proceeds via light-driven proton-coupled electron transfer (PCET) activation of the O?H bond in the allylic al

Vilsmeier Reaction on Some 1-Alkyl-1-arylallyl Alcohols: Benzannulation Leading to Biphenyl-mono- and Dicarboxaldehydes

1,1-Disubstituted alkylarylallyl alcohols (2a-d) have been prepared from alkyl aryl ketones (1a-d) by Grignard reaction with vinylmagnesium bromide and subjected to the action of phosphoryl chloride in dimethylformamide under Vilsmeier reaction conditions.The biphenyl-mono- (3a-d) and dicarboxaldehydes (4a-d) formed have been readily separated and fully characterized.