849599-06-0Relevant articles and documents
Rh-catalyzed alkene oxidation: a highly efficient and selective process for preparing N-alkoxysulfonyl aziridines
Guthikonda, Kiran,Wehn, Paul M.,Caliando, Brian J.,Du Bois
, p. 11331 - 11342 (2006)
Unique alkoxysulfonyl aziridine heterocycles were prepared through selective intra- and intermolecular alkene oxidation reactions. These methods are general and perform efficiently at low Rh-catalyst loadings (1-2 mol %) with only a slight excess of an in
GENERAL CATALYST FOR C-H FUNCTIONALIZATION
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Paragraph 0094; 0095; 0111; 0112; 0113; 0162; 0163; 0164, (2016/10/11)
The invention provides novel manganese catalysts such as [Mn(tBuPc)], which are general for the amination of all types of C(sp3)-H bonds (aliphatic, allylic, propargylic, benzylic, ethereal), including strong 1o aliphatic
Enantioselective intramolecular copper-catalyzed aziridination of sulfamates
Esteoule, Audrey,Duran, Fernando,Retailleau, Pascal,Dodd, Robert H.,Dauban, Philippe
, p. 1251 - 1260 (2008/02/04)
Intramolecular copper-catalyzed aziridination of sulfamates occurs in very good yields of up to 86% and in up to 84% ee in the presence of (4S,4′S)-2,2′-(propane-2,2-diyl)bis(4-tert-butyl-4,5-dihydro-1, 3-oxazole). The resulting aziridines undergo smooth
Tethered aminohydroxylation using acyclic homo-allylic sulfamate esters and sulfonamides as substrates
Kenworthy, Martin N.,Taylor, Richard J. K.
, p. 603 - 611 (2007/10/03)
Homo-allylic sulfamate esters and sulfonamides are shown to be useful substrates for the tethered aminohydroxylation (TA) reaction. The sulfamate esters undergo the TA reaction delivering 1,2,3-oxathiazinane products whereas the sulfonamides give 1,2-thia
