937-58-6

Basic information

• Product Name: 4-Phenyl-3-buten-1-ol
• Synonyms: 4-Phenyl-3-buten-1-ol
• CAS NO: 937-58-6
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.2
• Mol File: 937-58-6.mol
• Article Data: 94

Chemical Properties

• Melting Point: 36 °C
• Boiling Point: 99-101 °C(Press: 12 Torr)
• Appearance: /
• Density: 1.026±0.06 g/cm3(Predicted)
• PKA: 14.97±0.10(Predicted)
• CAS DataBase Reference: 4-Phenyl-3-buten-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Phenyl-3-buten-1-ol(937-58-6)
• EPA Substance Registry System: 4-Phenyl-3-buten-1-ol(937-58-6)

Safety Data

• Hazardous Substances Data: 937-58-6(Hazardous Substances Data)

Upstream product

• 2243-53-0 styrylacetic acid 
• 14580-93-9 2,2,2-Triphenyl-1,2-λ⁵-oxaphospholan 
• 100-52-7 benzaldehyde 
• 53045-69-5 3-chloro-2-phenyl-tetrahydro-furan 
• 60-29-7 diethyl ether 
• 28525-69-1 (4E)-5-phenyl-4-pentenoic acid 
• 110-86-1 pyridine 
• 67-56-1 methanol 
• 37464-85-0 methyl 5-phenylpent-4-enoate 
• 66680-87-3 (2-phenylvinyl)tributylstannane 
• 540-51-2 2-bromoethanol 
• 108-86-1 bromobenzene 
• 627-27-0 homoalylic alcohol 
• 26175-85-9 diethyl 4-(hydroxymethyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate 

Downstream Products

• 16133-83-8 tetrahydro-2-phenylfuran 
• 7515-57-3 Naphthalin-2-sulfonsaeure-<4-phenyl-but-3-en-1-ylester> 
• 144302-92-1 <<((E)-4-Phenylbut-3-en-1-yl)oxy>(thiocarbonyl)>imidazolide 
• 144302-93-2 O-(E)-Phenylbut-3-en-1-yl O-isopropyl thionocarbonate 
• 2134-29-4 3-Hydroxypropanal 
• 852247-66-6 4,4-dimethyl-2-(4-phenyl-but-3-enyl)-4H-isoquinoline-1,3-dithione 
• 849599-06-0 (E)-4-phenylbut-3-en-1-yl sulfamate 
• 1330074-82-2 C₁₉H₁₆ClNO 
• 5558-00-9 (4-bromo-1-buten-1-yl)benzene 
• 1352632-27-9 C₁₉H₁₆ClNO 
• 1352632-28-0 C₂₀H₁₈ClNO 
• 18328-11-5 3-benzyl propionaldehyde 

Relevant articles and documents

Radical C(sp3)-H Heck-type Reaction of N-Alkoxybenzimidoyl Chlorides with Styrenes to Construct Alkenols

We report the first radical C(sp3)-H Heck-type reaction of aliphatic alcohols for selective δ- and ?-alkenol synthesis by photoredox catalysis. N-Alkoxybenzimidoyl chlorides are developed as novel alkoxyl radical precursors with tunable redox potentials. Various alkenols can be constructed by the inert C(sp3)-H Heck-type reaction of 4-cyano-N-alkoxybenzimidoyl chlorides with styrene derivatives under redox-neutral conditions, which can be performed on the gram scale and can be easily derivatized.

Are bis(pyridine)iodine(i) complexes applicable for asymmetric halogenation?

Enantiopure halogenated molecules are of tremendous importance as synthetic intermediates in the construction of pharmaceuticals, fragrances, flavours, natural products, pesticides, and functional materials. Enantioselective halofunctionalizations remain

Nickel-Catalyzed 1,2-Carboamination of Alkenyl Alcohols

An alcohol-directed, nickel-catalyzed three-component umpolung carboamination of unactivated alkenes with aryl/alkenylboronic esters and electrophilic aminating reagents is reported. This transformation is enabled by specifically tailored O-(2,6-dimethoxybenzoyl)hydroxylamine electrophiles that suppress competitive processes, including undesired β-hydride elimination and transesterification between the alcohol substrate and electrophile. The reaction delivers the desired 1,2-carboaminated products with generally high regio- and syn-diastereoselectivity and exhibits a broad scope of coupling partners and alkenes, including complex natural products. Various mechanistic experiments and analysis of the stereochemical outcome with a cyclic alkene substrate, as confirmed by X-ray crystallographic analysis, support alcohol-directed syn-insertion of an organonickel(I) species.