849796-38-9

Basic information

• Product Name: Carbamic acid, [(1S,2E)-1-phenyl-2,5-hexadienyl]-, 1,1-dimethylethyl ester
• CAS NO: 849796-38-9
• Molecular Formula: C17H23NO2
• Molecular Weight: 273.375
• Mol File: 849796-38-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [(1S,2E)-1-phenyl-2,5-hexadienyl]-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [(1S,2E)-1-phenyl-2,5-hexadienyl]-, 1,1-dimethylethyl ester(849796-38-9)
• EPA Substance Registry System: Carbamic acid, [(1S,2E)-1-phenyl-2,5-hexadienyl]-, 1,1-dimethylethyl ester(849796-38-9)

Safety Data

• Hazardous Substances Data: 849796-38-9(Hazardous Substances Data)

Upstream product

• 849796-21-0 2,2,2-trichloro-N-[(1S,2E)-1-phenylhexa-1,5-dienyl]acetamide 
• 172925-28-9 trans-(S)-1-phenyl-1,5-hexadien-3-ol 
• 14371-10-9 (E)-3-phenylpropenal 
• 24424-99-5 di-tert-butyl dicarbonate 

Downstream Products

• 25705-52-6 (R)-phenylglycine hydrochloride 
• 33125-05-2 Boc-D-Phg-OH 
• 137284-11-8 (2R)-2-N-(tert-butoxycarbonyl)amino-2-phenylethanal 

Relevant articles and documents

Asymmetric allylboration of α,β-enals as a surrogate for the enantioselective synthesis of allylic amines and α-amino acids

(Chemical Equation Presented) Optically pure allylic amines have been synthesized from α,β-unsaturated aldehydes via allylboration with (-)-B-allyldiisopinocampheylborane, followed by Overman rearrangement. By incorporating crotyl and alkoxyallylboration, functionalization at δ-position was readily accomplished. By applying this methodology, the synthesis of several chiral α-amino acids has been achieved.