849907-28-4Relevant academic research and scientific papers
Cationic chiral surfactant based micelle-guided asymmetric Morita-Baylis-Hillman reaction
Shairgojray, Bashir Ahmad,Dar, Aijaz Ahmad,Bhat, Bilal A.
, p. 58 - 61 (2016/06/01)
Cationic chiral surfactant (1R, 2S)-(-)-N-dodecyl-N-methylephedrinium bromide (DMEB) was utilized for the first time in inducing asymmetry to Morita-Baylis-Hillman reaction in aqueous medium. Proton NMR studies carried out to determine the locus of the re
A highly efficient kinetic resolution of Morita-Baylis-Hillman adducts achieved by N-Ar axially chiral Pd-complexes catalyzed asymmetric allylation
Wang, Feijun,Li, Shengke,Qu, Mingliang,Zhao, Mei-Xin,Liu, Lian-Jun,Shi, Min
supporting information; experimental part, p. 12813 - 12815 (2012/01/05)
Palladium complexes with an axially chiral N-Ar framework have been developed. These complexes showed high stereoselectivities in asymmetric allylic arylation to achieve the kinetic resolution of Morita-Baylis-Hillman adducts, affording up to 99% ee of (E
Kinetic resolution of hindered Morita-Baylis-Hillman adducts by Rh(I)-catalyzed asymmetric 1,4-addition/β-hydroxyelimination
Wang, Yazhou,Feng, Xiangqing,Du, Haifeng
supporting information; experimental part, p. 4954 - 4957 (2011/11/29)
A kinetic resolution of hindered Morita-Baylis-Hillman adducts has been successfully achieved in excellent selectivities via Rh(I)-catalyzed asymmetric 1,4-addition/β-hydroxyelimination with the use of a chiral sulfinamide/olefin hybrid ligand. This study
MgI2-accelerated enantioselective Morita-Baylis-Hillman reactions of cyclopentenone utilizing a chiral DMAP catalyst
Bugarin, Alejandro,Connell, Brian T.
supporting information; experimental part, p. 2644 - 2646 (2010/07/08)
Fu's planar chiral DMAP catalyst efficiently promotes the asymmetric Morita-Baylis-Hillman reactions of cyclopentenone with a variety of aldehydes in the presence of MgI2 as a cocatalyst.
